Man-Elephant is an extremely silly low-tier villain, but he's one that repeatedly tries to foil She-Hulk. He's more of a running joke than a constant concern. Superboy packs a powerful punch, but he's a superhero who's struggled to establish his own identity, and this malaise has carried over to a lack of exciting enemies. Superboy has been able to do Superman justice, but he's seriously in need of a Lex Luthor Jr. The Masked Marauder is basically just a super petty guy in a costume who holds a grudge against Ted Kord.
He ostensibly has no real powers and he's unsuccessful in his mission. When Kord passes, he pivots his aggression to the new Blue Beetle, Jaime Reyes, but Reyes handles him with little consequence and he relents. Zatanna is a powerful spellcaster who's a member of the Justice League Dark, but her colorful character makes her seem more like a member of the X-Men.
She performs magic on stage as a performer and her talking backwards routine never gets old. A strong lineage of magic users has continued to grow through Zatanna Zatara's bloodline. Zatanna's fought against Allura, Ember, and Nicolas Nolan, but none of these have made for deeply satisfying battles. Iron Man is a major star as far as the Marvel Cinematic Universe is concerned, but in the comics he doesn't exactly experience the strongest cross-section of villains.
If Tony Stark has any sort of archenemy besides his own inner demons , it would be the Mandarin. However, in spite of the villain's persistence, there's a major disconnect between these two and they don't share the emotional resonance that great rivals should. Black Widow has always been a crucial cog in S. Black Widow is a deadly assassin, but she doesn't really have a persistent rival.
Taskmaster gives her a hard time, and will be in her upcoming film, but he's a villain that's not just specific to Black Widow. The Hulk is one of the strongest heroes in Marvel's ranks and because of that it can be difficult to find a foe worthy of his efforts.
Zzzax was a particularly misguided attempt to give the Hulk a genetically engineered foe, but the electric-based Zzzax never really stuck. Likewise, General Thunderbolt Ross and the Leader are persistent thorns in the Hulk's side, but these rivalries always feel half-baked. Honestly, it's been difficult for all of the various Robins and wards of Batman to find their own archenemies.
Usually they're stuck with Batman's runoff and even though Nightwing squares off against Deathstroke, he's more of an antagonist for the Teen Titans as a whole.
Tim Drake is a formidable fighter and even though his comics have tried to turn villains like King Snake and Anarchy into his personal Joker, none of these efforts have stuck. Daniel Kurland is a freelance writer, comedian, and critic, who lives in the cultural mosaic that is Brooklyn, New York. Plastic Man's archenemy is Dr.
Dome; a scientist with a dome hat. The Atom's archenemy is Chronos; a time traveler with the ability to manipulate history. Shazam's archenemy is Dr. Sivana; a mad scientist who commits crime with his family. Green Arrow's archenemy is Merlyn; a rival archer.
Blackhawk's archenemy is Killer Shark; a modern day pirate equipped with powerful submarines. The Watchmen's archenemy is Ozymandias; a former member that wants to save the entire world by destroying some of it. The Teen Titans' archenemy is Deathstroke; a mercenary with superhuman abilities. Jonah Hex's archenemy is Quentin Turnbull; an outlaw with a vengeance against Hex.
V's archenemy is Adam Susan; a dictator who does not let people live freely. The Justice League's archenemy is Darkseid; the supreme monarch of the planet Apokolips, he seeks to control all living things with the Anti-Life Equation.
Aquaman's archenemy is Black Manta; a scarred villain with dreams of ruling the sea. Firestorm's archenemy is Multiplex; a supervillain that can split into multiple clones. Raven's archenemy is Trigon; her all-powerful demonic father. Blue Beetle's archenemy is Masked Marauder; a masked gunman with a wrecked reputation. Nightwing's archenemy is Blockbuster; the crime lord of Bludhaven.
Spider Jerusalem's archenemy is Gary Callaham A. John Constantine, the Hellblazer's archenemy is the First of the Fallen, who is the true first angel to fall into Hell.
Booster Gold's archenemy is Jon Carter, a gambler who is constantly in debt. Marvel Comics Spiderman's archenemy is the Green Goblin; a masked criminal with insane tendencies. Hulk's archenemy is The Leader; an ambitious criminal who got irratiated with Gamma rays that caused him getting infinite knowledge. Professor X and X-Men's archenemy is Magneto and his Brotherhood of Mutants; a villain who has the ability to manipulate magnetic objects who wants to kill all non-mutants so the Homo Superior rule the Earth.
Thor's archenemy is Loki; his brother who causes mischief and terror everywhere he goes. Captain America's archenemy is Red Skull; a terrorist and an ex-nazi with the same abilities and physical durability as the Captain. The original champion of the Wizard, Teth-Adam was a former slave who channeled the power of six Egyptian Gods to fight evil.
But when his family was murdered during the conquest of his people, he developed more ruthless methods to protect innocents. After centuries of imprisonment, he would finally escape to overthrow Kahndaq's tyrant by force, becoming the country's defender and a natural enemy to the world's heroes. One of Hal Jordan's oldest foes, Black Hand has evolved from a gimmicky criminal into a sadistic madman capable of siphoning lifeforce from his victims. Reanimated after his suicide, he is now an avatar of the Black Lantern.
Blackfire is the older evil sister of Starfire and Darkfire. Brain Wave honed his mental abilities to perfection, enabling him to hypnotise people effortlessly, and to project realistic three-dimensional images. The ultimate physical specimen, Captain Nazi is an incomparable athlete and a master of hand to hand combat. The niece of the original Cheetah, Deborah Domaine was mind-controlled into serving as the second Cheetah.
Barbara Ann Minerva was an archaeologist who used an ancient ritual to turn herself into the avatar of Urzkartaga, but because she didn't meet the requirement of virginity, she was cursed by the god to suffer from an unending hunger for human flesh.
Deadshot is an expert marksman and usually associated with the Suicide Squad. He has gone from villain to anti-hero over the years, but it's difficult to strap him down to one hero, considering his work with the Squad. He has often operated against street level heroes like the Green Arrow, the Birds of Prey, and Batman. The Dark Knight may be the closest he has come to having an arch enemy, but even then their conflicts are usually not personal.
Bronze Tiger has also become a bit of an anti-hero in recent years thanks to his time with the Suicide Squad. He initially was brought up and trained by the League of Assassins, which is what makes him such a dangerous fighter.
Bronze Tiger has appeared in a variety of stories across the DC medium, but never has he repeatedly fought a specific hero. Tiger is more of a floating baddie and even in a team controlled by Amanda Waller, there's not an ongoing threat throughout their career. But none of these are his arch enemy since he is usually just fulfilling a job.
Even when something gets personal, there is an element of honor and duty to his actions. Slade Wilson has made so many enemies that it is difficult to attach him to just a singular hero in the same way as Zod or Cheetah.
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